Sunday, 6 January 2013

spectroscopy - Why is $g$ tied to the oscillator strength $f$ in $log{gf}_{odot}$

You don't make it clear, but you may be confused about what $g$ is. It is the statistical weight of an atomic energy level.



The $gf$ value, which refers to a particular transition between two energy levels in an atom/ion, is used because there is symmetry in terms of emission/absorption processes once the statistical weight is taken into account.
$$g_1 f_{12} = - g_2 f_{21}$$



If you just quoted $f$, then you would also need to know what the appropriate statistical weight was in order to calculate transition probabilities.

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