I have carried out the suggestion in the last paragraph of Yemon Choi's answer. Choose $phiin C^infty(mathbb{R})$, $phige0$ and $int_{mathbb{R}}phi(x)dx=1$, and let $phi_R(x)=Rphi(Rx)$. Define
$$ f=phi_Rstareta,quad g=eta-f.$$
Then it is easy to see that
$$ |f|_{C^n}=O(R^{n-alpha}),quad |g|_infty=O(R^{-alpha}),$$
but this is not what you are asking for.
My feeling is that the constant $C$ must show some dependence on $n$.
In response to your last comment, let me prove the estimate on $|f|_{C^n}$. We have
$$f^{(n)}=(phi_R)^{(n)}stareta=R^n(phi^{(n)})_Rstareta.$$
Since $(phi^{(n)})_R$ has mean zero, for any $xinmathbb{R}$:
$$ |f^{(n)}(x)|le R^nint_{mathbb{R}}|phi^{(n)}(y)||eta(x-frac{y}{R})-eta(x)|dyle HR^{n-alpha}int_{mathbb{R}}|phi^{(n)}(y)||y|^alpha dy,$$
where $H$ is $eta$'s Hölder constant.
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