I'm going to start by going over the Pauli Exclusion Principle. Basically, it says that two fermions (in this case, electrons) can't be in the same quantum state. To expand: No two electrons in an atom can share the same numbers for their four quantum numbers. What are quantum numbers? Well, I'll admit that Wikipedia describes them a lot better than I can, but the important thing here is that no two electrons can have the same spin and energy level. In a neutron star, the electrons are packed very close together, and there's quite a lot of force due to gravity. But the Exclusion Principle triumphs. Electrons near each other must have different energy levels; this leads to energy differences and pressure, which counteracts the force of gravity. Above a certain mass limit (the Chandrasekhar limit), at a stellar remnant weighing 1.39+ solar masses, gravity is too strong, and the stellar remnant becomes neutron star.
I hope this helps.
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