jc, you'll have fun working out answers to examples of your first question. I'm only going to address the Legendrian case. If I didn't make mistakes, I'll conclude that Legendrian immersions of $S^n$ into $S^{2n+1}$ are all regular homotopic if $n$ is even, while if $n$ is odd they are classified by a rotation number. For the second question, I'll just suggest that you think about 1-forms valued in the orientation line bundle.
The h-principle you quoted (cf. Eliashberg-Mishachev's book) tells us that we need to understand homotopy classes $[f,l]$, where $f$ is a map $L to M$ and $l colon TLotimes mathbb{C}to f^* xi$ an injective bundle map. Understanding the set $[L,M]$ of homotopy classes of unbased maps is an obstruction theory problem, and in general pretty intractable, but $[S^k,M]$ is the set of $pi_1(M)$-orbits in $pi_k(M)$. The fibre of the forgetful map $[f,l]mapsto [f]$ is exactly the set of injective bundle maps $l colon TLotimes mathbb{C}to f^ast xi$ (this is an application of the covering homotopy property of bundles, bearing in mind that the injective bundle maps themselves form a fibre bundle).
Now fix $f$. In the Legendrian case, what we're looking is $pi_0$ of the space $I(f)$ of isomorphisms $TLotimes mathbb{C}to f^ast xi$. In terms of classifying maps, $pi_0 I(f)$ is the set of homotopy classes of homotopies from $t_{mathbb{C}}$, the composite of the tangent map $tcolon L to BO(n)$ with $BO(n)to BU(n)$, to $tilde{xi}f$. Necessary conditions for $I(f)neq emptyset$ are that, for all $j$, $p_j(TL) = pm f^ast c_{2j}(xi)$ (I forget what the sign should be) and $2 f^ast c_{2j+1}(xi)=0$. When $L=S^n$, you have to compare two elements of $pi_n BU(n)=pi_{n-1}U(n) = pi_{n-1}U(infty)$ which is $mathbb{Z}$ or $0$ according to whether $n$ is even or odd. Since the Pontryagin classes of $S^n$ are zero by the signature theorem, I think what you actually have to check is whether $f^* c_{n/2}(xi)=0$.
If one isomorphism exists, there will be more: we can compose with any complex automorphism of $T^ast Lotimes mathbb{C}$. Up to homotopy, automorphisms correspond to isomorphism classes of vector bundles over $S^1times L$ extending $T^ast Lotimes mathbb{C}to L$, and so one has to classify such extensions. This is another obstruction theory problem. When $L=S^n$, any two extensions agree over $S^1 vee L$, and over the last $(n+1)$-cell they differ by a map $S^{n+1} to BU(n)$.
So, when $L=S^n$, there's a freely transitive action of $pi_{n+1}BU(n)=pi_n U(n) = pi_n U(infty)$ on $I(f)$.
Examples: say $M=S^{2n+1}$, $xi$ any contact structure, $L=S^n$, $f$ any map (necessarily homotopically trivial). Then $f^ast xi$ is trivial, so $I(f)$ is non-empty. It is a singleton if $n$ is even, and is a freely transitive $mathbb{Z}$-set if $n$ is odd. When $n=1$, the $mathbb{Z}$ should be the classical rotation number.
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